You will need to open and account with 2captcha.com.
Once you have an account you should be able to find the API key inside the account under 2captcha API section on the top menu.
Copy the key and paste it inside indexer on the section where it says "Please click to enter your 2captcha key for the best indexing rates" https://www.screencast.com/t/3cBNW39fAMn